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吴晓进教授课题组在ACS Catalysis发表研究论文
阅读次数: 添加时间:2020/12/01 发布:

Palladium-Catalyzed Intermolecular Polarity-Mismatched Addition of Unactivated Alkyl Radicals to Unactivated Alkenes

Xiaojin Wu,a* Guanlin Xiao,a Yalan Ding,a Ying Zhan,a Yao Zhao,a Rizhi Chen,c and Teck-Peng Lohb*

a Institute of Advanced Synthesis, School of Chemistry and Molecular Engineering, Nanjing Tech University, Nanjing 211816, China

b Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, Singapore 637616

c  State Key Laboratory of Materials-Oriented Chemical Engineering, Nanjing Tech University, Nanjing 211816, China


Abstract: A palladium-catalyzed intermolecular polarity-mismatched addition of unactivated alkyl radicals to unactivated alkenes was developed for the first time. In the two-component

dicarbofunctionalization, a variety of primary, secondary, and tertiary unactivated alkyl halides regioselectively reacted with various unactivated olefins. A series of structurally complex heteropolycycles decorated with a quaternary carbon center have been efficiently synthesized.

 

ACS Catal. 2020, 10, 14107−14116 (影响因子:12.35)

文章链接:https://dx.doi.org/10.1021/acscatal.0c04013

 

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